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Coin/Button Lithium Manganese Dioxide Batteries PRODUCT SAFETY DATA SHEET
PRODUCT NAME: Uniross Battery
Type No.:
Volts: 3.0
TRADE NAMES: Coin/Button Lithium Manganese Dioxide Batteries
Approximate Weight: 0.6 – 7.0 g
CHEMICAL SYSTEM: Lithium Manganese Dioxide
Designed for Recharge: No
SECTION 1- MANUFACTURER INFORMATION
Manufactured for Uniross Batteries South Africa Telephone Number for Information: Unit 1, Kyalami Crescent +27 (0) 11 466 1156 Kyalami Business Park, Midrand Date Prepared: January 2013 SECTION 2 – HAZARDS IDENTIFICATION
Under normal conditions of use, the battery is hermetically sealed. Ingestion: Swallowing may lead to serious injury or death in as little as 2 hours due to chemical burns and potential perforation of the
esophagus. Immediately see doctor. Do not induce vomiting or give food or drink.
Inhalation:
Contents of an open battery can cause respiratory irritation.
Skin Contact: Contents of an open battery can cause skin irritation.
Eye Contact:
Contents of an open battery can cause severe irritation.
SECTION 3 - INGREDIENTS

IMPORTANT NOTE:
The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be
harmful.
MATERIAL OR INGREDIENT
PEL (OSHA)
TLV (ACGIH)
(CAS# 1333-86-4) 1,2-Dimethoxyethane None established None established (CAS# 110-71-4) 1,3-Dioxolane None established None established (CAS# 646-06-0) Graphite 15 mg/m3 TWA (total dust) 2 mg/m3 TWA (respirable fraction) (CAS# 7782-42-5) 5 mg/m3 TWA (respirable fraction) Lithium or Lithium Al oy None established None established (CAS# 7439-93-2) Lithium Perchlorate None established None established (CAS# 7791-03-9) Lithium Trifluoromethanesulfonate None established None established (CAS# 33454-82-9) Lithium Trifluoromethanesulfonimide None established None established (CAS# 90076-65-6) Manganese Dioxide 5 mg/m3 Ceiling (as Mn) 0.2 mg/m3 TWA (as Mn) (CAS# 1313-13-9) Propylene Carbonate None established None established (CAS# 108-32-7) 2013 Uniross Batteries


Coin/Button Lithium Manganese Dioxide Batteries Non-Hazardous Components: None established None established (iron CAS# 7439-89-6) Plastic and Other None established None established SECTION 4 – FIRST AID MEASURES
Ingestion: Swallowing may lead to serious injury or death in as little as 2 hours due to chemical burns and potential perforation of the
esophagus. Immediately see doctor. Do not induce vomiting or give food or drink.
Inhalation: Provide fresh air and seek medical attention.
Skin Contact:
Remove contaminated clothing and wash skin with soap and water.
Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the
chemical remains. Seek medical attention.
Note: Carbon black is listed as a possible carcinogen by International Agency for Research on Cancer (IARC).
SECTION 5- FIRE FIGHTING MEASURES
In case of fire where lithium batteries are present, flood area with water or smother with a Class D fire extinguishant appropriate for lithium metal, such as Lith-X. Water may not extinguish burning batteries but wil cool the adjacent batteries and control the spread of fire. Burning batteries wil burn themselves out. Virtually all fires involving lithium batteries can be control ed by flooding with water. However, the contents of the battery wil react with water and form hydrogen gas. In a confined space, hydrogen gas can form an explosive mixture. In this situation, smothering agents are recommended. A smothering agent wil extinguish burning lithium batteries. Emergency Responders should wear self-contained breathing apparatus. Burning lithium manganese dioxide batteries produce toxic and corrosive lithium hydroxide fumes. SECTION 6 - ACCIDENTAL RELEASE MEASURES
To cleanup leaking batteries: Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries.
Respiratory Protection:
Avoid exposure to electrolyte fumes from open or leaking batteries.
Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery.
Gloves:
Use neoprene or natural rubber gloves if handling an open or leaking battery.
Battery materials should be col ected in a leak-proof container. SECTION 7 - HANDLING AND STORAGE

Storage:
Store in a cool, wel ventilated area. Elevated temperatures can result in shortened battery life. In locations that handle large quantities of
lithium batteries, such as warehouses, lithium batteries should be isolated from unnecessary combustibles.
Mechanical Containment: If potting or sealing the battery in an airtight or watertight container is required, consult your Uniross Batteries
representative for precautionary suggestions. Do not obstruct safety release vents on batteries. Encapsulation of batteries wil not allow cell venting and can cause high pressure rupture. Handling: Accidental short circuit for a few seconds wil not seriously affect the battery. Prolonged short circuit wil cause the battery to lose energy,
generate significant heat and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into devices. Damaging a lithium battery may result in an internal short The contents of an open battery, including a vented battery, when exposed to water, may result in a fire and/or explosion. Crushed or damaged batteries may result in a fire. If soldering or welding to the battery is required, consult your Uniross representative for proper precautions to prevent seal damage or short circuit. 2013 Uniross Batteries


Coin/Button Lithium Manganese Dioxide Batteries
Charging: This battery is manufactured in a charged state. It is not designed for recharging. Recharging can cause battery leakage or, in
some cases, high pressure rupture. Inadvertent charging can occur if a battery is installed backwards.
Labeling:
If the Uniross label or package warnings are not visible, it is important to provide a package and/or device label stating:
WARNING: Battery can explode or leak and cause burns if installed backwards, disassembled, charged, or exposed to water, fire or high temperature. Where accidental ingestion of smal batteries is possible, the label should include: (1) KEEP OUT OF REACH OF CHILDREN. Swallowing may lead to serious injury or death in as little as 2 hours due to chemical
burns and potential perforation of the esophagus. Immediately see doctor. Keep in original package until ready to use.
Dispose of used batteries immediately. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation Requirements: Not necessary under normal conditions.
Respiratory Protection: Not necessary under normal conditions.
Eye Protection: Not necessary under normal conditions.
Gloves: Not necessary under normal conditions.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point @ 760 mm Hg (°C) Not applicable for an Article Vapor Pressure (mm Hg @ 25°C) Not applicable for an Article Vapor Density (Air = 1) Not applicable for an Article Percent Volatile by Volume (%) Not applicable for an Article Evaporation Rate (Butyl Acetate = 1) Not applicable for an Article Solubility in Water (% by weight) Not applicable for an Article Not applicable for an Article Appearance and Odor Solid object / no odor SECTION 10 – STABILITY AND REACTIVITY
Lithium manganese dioxide batteries do not meet any of the criteria established in 40 CFR 261.2 for reactivity. 2013 Uniross Batteries


Coin/Button Lithium Manganese Dioxide Batteries SECTION 11 – TOXICOLOGICAL INFORMATION
Lithium manganese dioxide batteries are not hazardous waste. Under normal conditions of use, lithium manganese dioxide batteries are non-toxic. SECTION 12 – ECOLOGICAL INFORMATION
Issues such as ecotoxicity, persistence and bioaccumulation are not applicable for articles. SECTION 13 – DISPOSAL CONSIDERATIONS
Dispose of in accordance with all applicable federal, state and local regulations. SECTION 14 – TRANSPORT INFORMATION
In general, all batteries in all forms of transportation (ground, air, or ocean) must be packaged in a safe and responsible manner. Regulatory concerns from all agencies for safe packaging require that batteries be packaged in a manner that prevents short circuits and be contained in "strong outer packaging" that prevents spil age of contents. Al original packaging for Uniross lithium batteries are compliant with these regulatory concerns. Unirosss lithium coin batteries are exempt from the classification as dangerous goods as they meet the requirements of the special provisions listed below. (Essentially, they are properly packaged and labeled, contain less than 1 gram of lithium and pass the tests defined in UN model regulation section 38.3). Regulatory Body
Special Provisions
188, 230, 310, 636, 656 188, 230, 310, 957 UN 3090, UN 3091 29, A54, A100, A101 Packaging Instructions 968 - 970 SECTION 15 - REGULATORY INFORMATION
Outside of the transportation requirements noted in Section 14, lithium manganese dioxide batteries marketed by Uniross Batteries are not regulated. SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and Community Right-To- SECTION 16 - OTHER INFORMATION
2013 Uniross Batteries

Source: http://www.uniross.co.za/images/dataSheets/msds/Lithium%20Coin%20Cell%20MSDS.pdf

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